{"product_id":"eta2-complexes-of-group-10-with-cinnamic-acid-derivatives-spectroscopic-properties-stability-reactivity-and-application-potential-as-photo-switchab-paperback","title":"Eta2 Complexes of Group 10 with Cinnamic Acid Derivatives; Spectroscopic Properties, Stability, Reactivity and Application Potential as Photo-Switchab - Paperback","description":"\u003cdiv\u003e\u003cp style=\"text-align: right;\"\u003e\u003ca href=\"https:\/\/reportcopyrightinfringement.com\/\" target=\"_blank\" rel=\"nofollow\"\u003e\u003cb\u003eReport copyright infringement\u003c\/b\u003e\u003c\/a\u003e\u003c\/p\u003e\u003c\/div\u003e\u003cp\u003eby \u003cb\u003eMagnus R. Buchner\u003c\/b\u003e (Author)\u003c\/p\u003e\u003cp\u003eHomogeneous catalysts based on transition metals are of high industrial relevance. An important goal for this purpose is the light-induced start of the catalytic reaction. The electronic and steric influence of the olefin ligand upon the spectroscopic properties, stability and reactivity of bistriphenylphosphine-cinnamate and related complexes of group 10 were studied in this thesis. By means of these findings a direct prediction of the reactivity was possible based on the NMR-spectroscopic behaviour. Thus a specific design of photo-switchable complexes was possible, in which the olefin ligand could be cleaved from the metal via a selective light-induced intra-ligand cyclisation. This ring closure was examined with the ligand itself as well as in the complexes, concerning electronic and steric influences.\u003c\/p\u003e\n            \u003cdiv\u003e\n\u003cstrong\u003eNumber of Pages:\u003c\/strong\u003e 629\u003c\/div\u003e\n            \u003cdiv\u003e\n\u003cstrong\u003eDimensions:\u003c\/strong\u003e 1.35 x 9.46 x 6.7 IN\u003c\/div\u003e\n            \u003cdiv\u003e\n\u003cstrong\u003ePublication Date:\u003c\/strong\u003e February 19, 2014\u003c\/div\u003e\n            ","brand":"BooksCloud","offers":[{"title":"Default Title","offer_id":48760485642489,"sku":"9783832528478","price":185.4,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0789\/2782\/3097\/files\/S-5Iwm0XGV9783832528478.webp?v=1786034222","url":"https:\/\/bookscloud.io\/products\/eta2-complexes-of-group-10-with-cinnamic-acid-derivatives-spectroscopic-properties-stability-reactivity-and-application-potential-as-photo-switchab-paperback","provider":"BooksCloud Book Dropshipping","version":"1.0","type":"link"}