{"product_id":"synthesis-and-application-of-2-2paracyclophane-derivatives-in-catalysis-and-material-science-paperback","title":"Synthesis and Application of [2.2]paracyclophane Derivatives in Catalysis and Material Science - Paperback","description":"\u003cdiv\u003e\u003cp style=\"text-align: right;\"\u003e\u003ca href=\"https:\/\/reportcopyrightinfringement.com\/\" target=\"_blank\" rel=\"nofollow\"\u003e\u003cb\u003eReport copyright infringement\u003c\/b\u003e\u003c\/a\u003e\u003c\/p\u003e\u003c\/div\u003e\u003cp\u003eby \u003cb\u003eChristoph Zippel\u003c\/b\u003e (Author)\u003c\/p\u003e\u003cp\u003e[2.2]Paracyclophane is a prevalent p-stacked, carbocyclic scaffold with a \"bent and battered\" structure. This results not only in a transannular communication but also in a chiral plane within the molecule if at least one substituent is present. These unique properties make this structure synthetically challenging but also scarcely investigated. A new method for enantio-separation based on kinetic resolution was developed, which allows the access to enantiomerically pure [2.2]paracyclophane-based building blocks. In a liquid crystal templated chemical vapor deposition process, [2.2]paracyclophanyl alcohols containing an additional central chiral element were evaluated for the self-assembly of nanofibers. Furthermore, the cyclopropanation of a-alkyl-a-diazo compounds with a [2.2]paracyclophane-based rhodium tetracarboxylate complex was investigated. Finally, the rigidity, regioselective functionalization, and transannular communication of [2.2]paracyclophane were exploited in the design of heterobimetallic Au(I)\/Ru(II) complexes for the study of metal-to-metal interactions.\u003c\/p\u003e\n            \u003cdiv\u003e\n\u003cstrong\u003eNumber of Pages:\u003c\/strong\u003e 215\u003c\/div\u003e\n            \u003cdiv\u003e\n\u003cstrong\u003eDimensions:\u003c\/strong\u003e 0.48 x 8.04 x 5.68 IN\u003c\/div\u003e\n            \u003cdiv\u003e\n\u003cstrong\u003ePublication Date:\u003c\/strong\u003e November 30, 2021\u003c\/div\u003e\n            ","brand":"BooksCloud","offers":[{"title":"Default Title","offer_id":48632700666105,"sku":"9783832554125","price":122.4,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0789\/2782\/3097\/files\/XPqtqi6zH9783832554125.webp?v=1783138689","url":"https:\/\/bookscloud.io\/products\/synthesis-and-application-of-2-2paracyclophane-derivatives-in-catalysis-and-material-science-paperback","provider":"BooksCloud Book Dropshipping","version":"1.0","type":"link"}